Assembly and disassembly of a Zn10 high-nuclearity circular helicate.
نویسندگان
چکیده
A nano-scale decanuclear Zn(II) circular helicate is synthesized without the aid of counteranions during the assembly process, and can be totally disassembled into its reactants by specific anions.
منابع مشابه
Controlling the formation of metallosupramolecular assemblies by metal ionic radiiw
Controlling the structure of multi-component assemblies is one of the leading challenges for the supramolecular chemist. One of the simplest assemblies is the dinuclear doublestranded helicate, and the rules that govern the formation of this species are largely established. The formation of the helicates’ higher nuclearity cousin, the cyclic helicate, is conversely less well understood. One of ...
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 28 شماره
صفحات -
تاریخ انتشار 2012